History
(Gr. hydro, water, and genes, forming)
Hydrogen was prepared many years before it was recognized as a distinct substance by Cavendish in 1776.
Named by Lavoisier, hydrogen is the most abundant of all elements in the universe, and it is thought that the heavier elements were, and still are, being built from hydrogen and helium.
Sources
Hydrogen is estimated to make up more than 90% of all the atoms or three quarters of the mass of the universe.
This element is found in the sun and most stars, and plays an important part in the proton-proton reaction and carbon-nitrogen cycle, which accounts for the energy of the sun and stars.
Hydrogen is thought to be a major component of Jupiter and that at some depth in the planet's interior the pressure is so great that solid molecular hydrogen is converted to solid metallic hydrogen.
In 1973, a group of Russian experimenters may have produced metallic hydrogen at a pressure of 2.8 Mbar.
At the transition the density changed from 1.08 to 1.3 g/cm^3.
Earlier, in 1972, a Livermore, California, a group also reported on a similar experiment in which they observed a pressure-volume point centered at 2 Mbar.
Predictions say that metallic hydrogen may be metastable; others have predicted it would be a superconductor at room temperature.
Compounds
On earth, hydrogen occurs chiefly in combination with oxygen in water, but it is also present in organic matter such as living plants, petroleum, coal, etc.
It is present as the free element in the atmosphere, but only to the extent of less than 1 ppm by volume.
The lightest of all gases, hydrogen combines with other elements -- sometimes explosively -- to form compounds.
Uses
Great quantities are required commercially for the fixation of nitrogen from the air in the Haber ammonia process and for the hydrogenation of fats and oils.
It is also used in large quantities in methanol production, in hydrodealkylation, hydrocracking, and hydrodesulfurization. Other uses include rocket fuel, welding, producing hydrochloric acid, reducing metallic ores, and filling balloons.
The lifting power of 1 ft^3 of hydrogen gas is about 0.07 lb at 0C, 760 mm pressure.
Production of hydrogen in the U.S. alone now amounts to about 3 billion cubic feet per year.
Hydrogen is prepared by
- steam on heated carbon,
- decomposition of certain hydrocarbons with heat,
- action of sodium or potassium hydroxide on aluminum
- electrolysis of water, or
- displacement from acids by certain metals.
Liquid hydrogen is important in cryogenics and in the study of superconductivity, as its melting point is only 20 degrees above absolute zero.
Tritium is readily produced in nuclear reactors and is used in the production of the hydrogen bomb.
It is also used as a radioactive agent in making luminous paints, and as a tracer.
Consideration is being given to an entire economy based on solar- and nuclear-generated hydrogen. Public acceptance, high capital investment, and the high cost of hydrogen with respect to today's fuels are but a few of the problems facing such an economy.
Located in remote regions, power plants would electrolyze seawater; the hydrogen produced would travel to distant cities by pipelines.
Pollution-free hydrogen could replace natural gas, gasoline, etc., and could serve as a reducing agent in metallurgy, chemical processing, refining, etc.
It could also be used to convert trash into methane and ethylene.
Forms
Quite apart from isotopes, it has been shown that under ordinary conditions hydrogen gas is a mixture of two kinds of molecules, known as ortho- and para-hydrogen, which differ from one another by the spins of their electrons and nuclei.
Normal hydrogen at room temperature contains 25% of the para form and 75% of the ortho form.
The ortho form cannot be prepared in the pure state.
Since the two forms differ in energy, the physical properties also differ.
The melting and boiling points of parahydrogen are about 0.1C lower than those of normal hydrogen.
Isotopes
The ordinary isotope of hydrogen, H, is known as Protium, the other two isotopes are Deuterium and Tritium. Hydrogen is the only element whose isotopes have been given different names. Deuterium and Tritium are both used as fuel for nuclear fusion reactors. One atom of Deuterium is found in about 6000 ordinary hydrogen atoms.
Deuterium is used as a moderator to slow down neutrons. Tritium atoms are also present but in much smaller proportions. Tritium is readily produced in nuclear reactors and is used in the production of the hydrogen (fusion) bomb. It is also used as a radioactive agent in making luminous paints, and as a tracer.
